Nanopartaculas (que tem tamanhos que variam entre 3-500 nm) e sub-nanoclusters (que tem cerca de 1 nm de dia¢metro) são utilizados em muitos campos, incluindo medicina, roba³tica, ciência de materiais e engenharia.
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)
Esta ilustração cientafica do estudo, criada pelo Dr. Takamasa Tsukamoto da Tokyo Tech, foi selecionada como uma Imagem de Capa Interna na Angewandte Chemie International Edition.Fonte da imagem: Dr. Tsukamoto, Tokyo Tech. Crédito: Dr Takamasa Tsukamoto de Tokyo Tech
Nanopartaculas (que tem tamanhos que variam entre 3-500 nm) e sub-nanoclusters (que tem cerca de 1 nm de dia¢metro) são utilizados em muitos campos, incluindo medicina, roba³tica, ciência de materiais e engenharia. Seu tamanho pequeno e grandes proporções de área desuperfÍcie para volume lhes conferem propriedades únicas, tornando-os valiosos em uma variedade de aplicações, desde controle de poluição atésantese química.
Recentemente, quase-sub-nanomateriais, que tem cerca de 1 a 3 nm em escala, tem atraado a atenção porque tem uma natureza dupla oseles podem ser considerados nanopartaculas , bem como moléculas inorga¢nicas. Compreensivelmente, controlar o número de a¡tomos em um quase-sub-nanomateriais pode ser de muito valor. No entanto, sintetizar estruturas moleculares tão precisas étecnicamente desafiador, mas os cientistas da Tokyo Tech certamente estavam prontos para esse desafio.
Dendrons - estruturas moleculares altamente ramificadas consistindo de iminas ba¡sicas - foram sugeridos como precursores para a santese precisa de quase-sub-nanomateriais com o número desejado de a¡tomos. As iminas nos dendrons funcionam como um andaime que pode formar complexos com certos sais meta¡licos a¡cidos, acumulando metais na estrutura do dendron. Estes, por sua vez, podem ser reduzidos a sub-nanoclusters meta¡licos com o número desejado de a¡tomos. No entanto, sintetizar dendrons com alta proporção de iminas éum processo caro e com baixo rendimento.
Agora, em um estudo publicado na Angewandte Chemie , os pesquisadores explicam como combinaram várias estruturas dendrameras para formar uma ca¡psula supramolecular composta por mais de 60 iminas. “A santese de supramoléculas montadas em dendrons foi realizada conectando unidades centrais internas e unidades externas de dendrons osque determinam a estrutura central e os ramos terminais, respectivamenteâ€, explica o professor assistente Takamasa Tsukamoto, envolvido no estudo. A estrutura interna desta supramolanãcula continha um núcleo de seis pontas com tritalio a¡cido, enquanto cada unidade externa continha dendrons com iminas. A interação entre o núcleo a¡cido e a estrutura externa ba¡sica resultou em um organocomplexo de automontagem.
aons de tritalio e aons de ra³dio são coacumulados com iminas introduzidas na unidade dendron para formar organo-complexos e metalo-complexos. Neste estudo,
o organocomplexo foi utilizado para a santese das ca¡psulas supramoleculares.
Crédito: Dr. Tsukamoto, Tokyo Tech
Além disso, as iminas foram coacumuladas com sais de ra³dio, de modo que as iminas mais internas formaram um complexo com unidades de tritalio, enquanto as mais externas foram preenchidas com os sais de ra³dio. A supramolanãcula resultante, que tinha uma unidade central interna cercada por seis unidades dendron externas (cada uma contendo 14 sais de ra³dio nas iminas externas), foi condensada com sucesso em aglomerados contendo 84 a¡tomos de ra³dio com um tamanho de 1,5 nm.
Ao anexar dendrons contendo imina a um núcleo a¡cido, os pesquisadores construaram um modelo supramolecular para a santese de quase-sub-nanomateriais. Além disso, uma vez que as iminas podem formar complexos com uma ampla gama de unidades catia´nicas, o manãtodo pode ser usado para sintetizar uma variedade de estruturas supramoleculares. Devido a sua versatilidade, simplicidade e custo-benefacio, o manãtodo pode ser uma pedra angular para o desenvolvimento de novos nanomateriais. "Esta nova abordagem para obter quase-sub-nanomateriais definidos por atomicidade sem as limitações dos manãtodos convencionais tem o potencial de desempenhar um papel importante na exploração das últimas fronteiras dos nanomateriais", diz o Prof. Tsukamoto. De fato, este pode ser um passo "pequeno" para a Tokyo Tech, mas um passo "gigante" para a nanociência